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Nylons (Polyamides) PA semi-crystalline

INTRODUCTION
The name "nylons" refers to the group of plastics known as polyamides. Nylons are typified by amide groups (CONH) and encompass a range of material types (e.g. Nylon 6,6; Nylon 6,12; Nylon 4,6; Nylon 6; Nylon 12 etc.), providing an extremely broad range of available properties. Nylon is used in the production of film and fibre, but is also available as a moulding compound.

PROPERTIES
The majority of nylons tend to be semi-crystalline and are generally very tough materials with good thermal and chemical resistance. The different types give a wide range of properties with specific gravity, melting point and moisture content tending to reduce as the nylon number increases.

Nylons tend to absorb moisture from their surroundings. This absorption continues until equilibrium is reached and can have a negative effect on dimensional stability. In general, the impact resistance and flexibility of nylon tends to increase with moisture content, while the strength and stiffness below the glass transition temperature (< 50-80 oC) decrease.

Grades Available
There are many types of nylon available (e.g. Nylon 6 nylon 66, nylon 6/6-6, nylon 6/9, nylon 6/10, nylon 6/12, nylon 11, nylon 12). The material is available as a homopolymer, co-polymer or reinforced. Nylons may also be blended with other engineering plastics to improve certain aspects of performance.

Psysical properties:

Tensile Strength

56 - 90

MPa

E-modulus

1000 - 2600

MPa

Notched Impact Strength

5.0 - no break

kJ/m²

Thermal Coefficient of expansion

90

x 10-6

Max Cont Use Temp

168 - 250

0C

VicatB Temp

80 - 150

0C

Density

1.02 - 1.13

g/cm³

Resistance to chemicals:

Dilute Acid

Poor

Dilute Alkalis

Good

Oils and Greases

Very good

Aliphatic Hydrocarbons

Very good

Aromatic Hydrocarbons

Very good

Halogenerated Hydrocarbons

Good

Density

Poor


APPLICATIONS
Nylon fibres are used in textiles, fishing line and carpets. Nylon films is used for food packaging, offering toughness and low gas permeability, and coupled with its temperature resistance, for boil-in-the-bag food packaging.

Mouldings and profiles find many applications as replacements for metal parts, for instance in car engine components. Intake manifolds in nylon are tough, corrosion resistant, lighter and cheaper than aluminium. Its self-lubricating properties make it useful for gears and bearings.

Electrical insulation, corrosion resistance and toughness make nylon a good choice for high load parts in electrical applications as insulators, switch housings and cable ties. Another major application is for power tool housings.

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